|
|
methylglyoxal + D-fructose_1,6-bisphosphate <=> D-glyceraldehyde_3-phosphate + 1-deoxy-D-threo-hexo-2,5-diulose_6-phosphate
|
2.2.1.11
6-deoxy-5-ketofructose 1-phosphate synthase
|
–
|
|
BRENDA:
BR50117
KEGG:
R10049
MetaCyc:
RXN-10053
|
|
|
|
L-aspartate + ATP <=> L-4-aspartyl_phosphate + ADP
|
2.7.2.4
aspartate kinase
|
–
|
|
BRENDA:
BR47827
KEGG:
R00480
MetaCyc:
ASPARTATEKIN-RXN
SABIO-RK:
912
|
|
|
|
1-deoxy-D-threo-hexo-2,5-diulose_6-phosphate + L-aspartate_4-semialdehyde <=> 2-amino-3,7-dideoxy-D-threo-hept-6-ulosonate + 2,3-dioxopropyl_phosphate
|
2.2.1.10
2-amino-3,7-dideoxy-D-threo-hept-6-ulosonate synthase
|
–
|
|
BRENDA:
BR50116
KEGG:
R08568
MetaCyc:
RXN-10031
|
|
|
|
L-aspartate_4-semialdehyde + phosphate + NADP+ <=> L-4-aspartyl_phosphate + NADPH + H+
|
1.2.1.11
aspartate-semialdehyde dehydrogenase
|
–
|
|
BRENDA:
BR36772
KEGG:
R02291
MetaCyc:
ASPARTATE-SEMIALDEHYDE-DEHYDROGENASE-RXN
SABIO-RK:
2255
|
|
|
|
enolaldehyde <=> methylglyoxal
|
0.0.0.0
|
–
|
|
BRENDA:
BR52893
MetaCyc:
RXN-10054
|
|
|
|
2-amino-3,7-dideoxy-D-threo-hept-6-ulosonate + H2O + NAD+ <=> 3-dehydroquinate + NH3 + NADH + H+
|
1.4.1.24
3-dehydroquinate synthase II
|
–
|
|
BRENDA:
BR50242
KEGG:
R08569
MetaCyc:
RXN-10032
|
|
|
|
D-glyceraldehyde_3-phosphate <=> enolaldehyde + phosphate
|
4.2.3
|
–
|
|
MetaCyc:
RXN-8075
|
|